Cationic polymerization of isobutyl vinyl ether ibve was examined using a variety of metal halides. X i br cl initiating systems in toluene at 15 c in the presence of acetone and the three benzaldehydes me 3 sil znl 2 induced living cationic. Living cationic polymerization of isobutul vinyl ether ibve initiated by1 iodo 1 2 methyl propyloxy ethane 1 and tetraalkylammonium perchlorate yields polymers of well defined molar masses and end groups.
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